Product ID:FERRIC SULFATE SOLUTION
MSDS Date:01/10/1990
FSC:6810
NIIN:00N054320
MSDS Number: BVWNM

VAN WATERS & ROGERS INC

6100 CARILLON POINT
KIRKLAND, WA 98033
US

Emergency Phone: 206-889-3400;800-424-9300(CHEMTREC)

Info Phone: 206-872-5000

Cage: DO735

VOPAK USA INC

KIRKLAND, WA 98033-7357 US

Telephone: 425-889-3400/425-889-3617

Cage: 0STM5

IRON (III) SULFATE; (FERRIC SULFATE) (SARA III)

CAS: 10028-22-5

RTECS: NO8505000

Fraction By Weight: 48.7%

OSHA PEL 1 MG/M3

ACGIH TLV: 1 MG/M3

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

SULFURIC ACID (SARA III)

CAS: 7664-93-9

RTECS: WS5600000

Fraction By Weight: 1.3%

OSHA PEL 1 MG/M3

ACGIH TLV: 1 MG/M3

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

WATER

CAS: 7732-18-5

RTECS: ZC0110000

Fraction By Weight: BALANCE

OSHA PEL N/K

ACGIH TLV: N/K

DOT-APPRVD WASTE CNTNRS. FOR LARGE SPILLS, CONTAIN

RTECS: 9999999ZZ

CAREFULLY NEUTRALIZE W/SODA ASH OR LIME. IF SODA ASH

RTECS: 9999999ZZ

DIOXIDE GAS. KEEP NON-NEUT MATL OUT OF SEWERS, STORM

RTECS: 9999999ZZ

REGS ON SPILL REPORTING & HANDLING & DISPOSAL OF

RTECS: 9999999ZZ

SUBJECT TO PROPER WASTE DISPOSAL.

RTECS: 9999999ZZ

GET IN EYES, ON SKIN OR ON CLTHG. STORAGE

RTECS: 9999999ZZ

PLASTICS, RUBBER, LEAD, TYPE 304 OR BETTER GRADES OF

RTECS: 9999999ZZ

WITH FULL LENGTH FACESHIELD .

RTECS: 9999999ZZ

MEETS ANSI DESIGN CRITERIA .

RTECS: 9999999ZZ

LD50 LC50 Mixture:LD50: (ORAL, RAT) 2.5-5 G/KG
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:INHAL: VAPORS & MISTS ARE EXTREMELY
CORROSIVE TO THE NOSE, THROAT & MUCOUS MEMBRANES. EYES: LIQUID &
MISTS ARE CORROSIVE TO EYES. BRIEF CONTACT OF LIQUID OR MISTS WILL
SEVERELY DAMAGE EYES & PROLONGED CONTACT MAY CAUSE PERMANENT EYE
INJURY. SKIN: NO IRRITATION IS LIKELY AFTER BRIEF CONTACT BUT MAY
BE (EFTS OF OVEREXP)
Explanation of Carcinogenicity:SULFURIC ACID:IARC MONOGRAPHS ON
EVALUATION OF CARCIN RISK OF CHEMS TO MAN,VOL 54, PG 41, 1992:GRP
1. ANIMAL:PULM IRRIT.
Effects of Overexposure:HLTH HAZ: IRRITATING AFTER PROLONGED CONTACT.
INGEST: MISTS & LIQUID ARE CORROSIVE TO THE MOUTH & THROAT &
RESPIRATORY TRACT. SWALLOWING THE LIQUID BURNS THE TISSUES, CAUSES
SEVERE ABDOMINAL PAIN, NAU SEA, VOMITING & COLLAPSE. CHRONIC: NO
SPECIFIC INFORMATION AVAILABLE.
Medical Cond Aggravated by Exposure:NONE REPORTED.

First Aid:INHAL: REMOVE TO FRESH AIR. GIVE ARTF RESP IF NOT BRTHG. GET
IMMED MED ATTN. EYES: IMMED FLUSH EYES W/LOTS OF RUNNING WATER FOR
AT LEAST 15 MIN, LIFTING UPPER & LOWER LIDS OCCAS. GET IMMED MED
ATTN. S KIN: IMMED FLUSH SKIN W/LOTS OF RUNNINGWATER FOR 15 MIN.
REMOVE CONTAMD CLTHG & SHOES; WASH BEFORE REUSE. GET IMMED MED
ATTN. INGEST: DO NOT INDUCE VOMIT. IF CONSCIOUS, GIVE LOTS OF WATER
OR (SUPDAT)

Flash Point:NONE
Extinguishing Media:THIS MATERIAL IS NOT COMBUSTIBLE. USE EXTINGUISHING
MEDIA APPROPRIATE FOR SURROUNDING FIRE.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT . USE WATER SPRAY TO COOL NEARBY CONTAINERS
AND STRUCTURES EXPOSED TO FIRE.
Unusual Fire/Explosion Hazard:NONE REPORTED.

Spill Release Procedures:WEAR ACID-RESISTANT SLICKER SUIT & COMPLETE
PROT EQUIP INCL RUB GLOVES, RUB BOOTS & NIOSH/MSHA APPRVD SCBA IN
PRESS DEMAND MODE OR SUPPLIED-AIR RESP. IF SPILL/LEAK IS SMALL,
NIOSH/MSHA APPRVD FULL FAC E-PIECE AIR-PURIFYING CARTRIDGE RESP
(SUPDAT)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE IN COOL, DRY, WELL-VENT PLACE
AWAY FROM INCOMPAT MATLS. KEEP CNTNR TIGHTLY CLSD WHEN NOT IN USE.
DO NOT USE PRESS TO EMPTY CNTNR. DO NOT (ING 9)
Other Precautions:CONTAINERS, EVEN THOSE THAT HAVE BEEN EMPTIED, WILL
RETAIN PRODUCT RESIDUE AND VAPORS. ALWAYS OBEY HAZARD WARNINGS &
HANDLE EMPTY CONTAINERS AS IF THEY WERE FULL.

Respiratory Protection:IF USE CNDTNS GENERATE MISTS, WEAR NIOSH/MSHA
APPRVD RESP APPROP FOR THOSE EMISSION LEVELS. APPROP RESPS MAY BE
FULL FACEPIECE AIR-PURIFYING CARTRIDGE RESP EQUIPPED FOR ACID
GASES/MISTS, SCBA IN PRESS URE DEMAND MODE OR SUPPLIED-AIR RESP.
Ventilation:LOCAL MECHANICAL EXHAUST VENTILATION CAPABLE OF MAINTAINING
EMISSIONS AT POINT OF USE BELOW THE PEL.
Protective Gloves:RUBBER GLOVES WITH GAUNTLETS.
Eye Protection:ANSI APPRVD CHEM WORKER GOGGLES (ING 11)
Other Protective Equipment:ACID-RESISTANT SLICKER SUIT W/RUB APRON, RUB
BOOTS W/PANTS OUTSIDE. EMERG EYE WASH AND DELUGE SHOWER WHICH (ING
12)
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. CONTACT LENSES
SHOULD NOT BE WORN WHEN WORKING WITH CHEMICALS.
Supplemental Safety and Health
MATLS TO AVOID: GALVANIZED STEEL, PAINTS, ENAMELS & CONCRETE. FIRST AID
PROC: MILK. GET IMMED MED ATTN. DO NOT GIVE ANYTHING BY MOUTH TO
UNCON OR CONVULSING PERSON. SPILL PROC: EQUIPPED FOR ACID MISTS
MAY BE SATISFACTORY. IN ANY EVENT, ALWAYS WEAR EYE PROT. FOR SM
SPILLS/DRIPS, MOP/WIPE UP & DISPOSE OF IN (ING 4)

HCC:N1
Boiling Pt:B.P. Text:212F,100C
Melt/Freeze Pt:M.P/F.P Text:<0F,<-18C
Spec Gravity:1.48 (H*2O=1)
Solubility in Water:55%
Appearance and Odor:RED CLEAR LIQUID; ODORLESS.

Stability Indicator/Materials to Avoid:YES
REACTS W/LIME & OTHER BASIC MATLS TO FORM INSOLUBLE IRON SALTS.
SOLUTION IS CORR TO MILD STEEL, COPPER ALLOYS, (SUPDAT)
Stability Condition to Avoid:TEMPERATURES ABOVE 1112F.
Hazardous Decomposition Products:AT TEMPERATURES ABOVE 1112F (600C) MAY
LIBERATE IRON OXIDE AND SULFUR TRIOXIDE.

Waste Disposal Methods:DISPOSE OF CONTAMD PROD & MATLS USED IN CLEANING
UP SPILLS/LEAKS IN MANNER APPRVD FOR THIS MATL. CONSULT APPROP FED,
STATE & LOCAL REGULATORY AGENCIES TO ASCERTAIN PROPER DISP PROC.
NOTE: EMPTY CNTNRS CAN HAVE RESIDUES, GASES & MISTS & ARE(ING 8)

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.